NATURAL HAZARD 










India is vulnerable to different natural hazards due to its proximity to geodynamically active regions and unique climatic pattern. Both these factors in different combinations lead to the occurrence of disasters resulting from natural hazards like floods, earthquakes, draught, cyclones and landslides in different parts of the country at frequent intervals. 

It is estimated that about 60% of landmass of the country is vulnerable to earthquakes of different magnitudes; about 8% of total area is susceptible to cyclone hazard; about 68% of the area is draught prone; 12% of area is susceptible to floods and approximately 15% of total area of the country is susceptible to landslides. 

The disaster situation in the country is further compounded by increased vulnerabilities related to rapidly growing population, unplanned urbanization and fast-paced industrialization, rapid development in high risk areas, environmental degradation and climate change. It is observed that impact of natural disasters is felt more severely by people who are socioeconomically weak because their habitats are located in vulnerable areas and not designed to withstand the impact of natural disasters. Therefore, the processes of poverty eradication and disaster management are intricately linked.

The severity of natural disasters in the country is indicated by the estimate of the Ministry of Home Affairs which states that in the decade 1990-2000, annually, an average of about 4344 people lost their lives and about 30 million people were affected by disasters. In recent years, a rising trend in both natural as well as man made disasters is evident. Statistics indicates that during 1994-1998, approximately 120 million were affected by the natural disasters and economic losses resulting from same during the period were estimated to be Rs. 286780 million. These figures climbed to 560 million and Rs. 474640 million during 1998-2003.

Floods, Drought, Cyclones, Hurricanes, Earthquakes, Landslides, Forest fires, Volcanic eruption, etc are some of the Natural Disasters that strike very frequently and cause devastating impact on human life, economy, natural resources and environment. Natural disasters seriously disrupt the functioning of a community or a region causing widespread human, material or environmental losses. 
The time scale of disasters differs from very short duration of a few seconds for earthquakes to a few minutes for volcano, a few hours for cyclone, a few days for flood and months or even years for drought. Though it is very difficult to control totally the occurrence of natural disasters, however, it is possible to reduce the impact of disasters by adopting suitable disaster mitigation measures.

We can only attempt to reduce the hazard to life and property. To combat the increasing risk we need more studies to attempt to understand and help forecast future events. We need to be able to monitor the hazardous systems (e.g. volcano monitoring, meteorological/ weather monitoring) and to be able to quickly communicate the information from the scientists to the general population.
All of this helps with the aim to MITIGATE (reduce) the effect of the natural hazards.
There are many types of natural events that can impact human processes:
Volcanoes, floods, earthquakes, tornadoes, tsunamis, landslides, avalanches, forest fires etc
These events can occur either without warning, for example an earthquake. Or they may occur with warning, for example you can monitor with satellites when and where a cyclone will hit the coastline. Also, some volcanoes change their behaviour before an eruption, the sides of the volcano may swell and crack as hot molten rock is pushed up towards the surface. These warnings are called “precursors”. Precursors are what scientists look out for when trying to forecast a future event.
To help forecast an event and mitigate (reduce) the hazards involved scientists need to know three things:  (1)The Frequency of the event, i.e. how often the event occurs (on a scale of every month, year, 10 years, 1000 years etc.)
(2)The Magnitude of the event, i.e. how powerful the event is. This often relates to how destructive the event is. There is an important link between frequency and magnitude: for example, an event with a high F and low M may not be as devastating and a hazard with low F but high M.
(3) The Scope of an event describes the area the hazard effects. Will the hazard or damage be contained only locally (e.g. landslides, fires, floods and earthquakes), or on a larger regional scale (e.g. tsunami’s, explosive volcanoes, large-scale earthquakes, cyclones). The largest, most catastrophic events may even affect the entire globe (e.g. large volcanoes, global warming, meteorite impacts). Knowing these three factors for each natural hazard event will help the population to plan for future events.

An earthquake is a sudden release of stored energy in the Earth’s crust. For example, this can be caused by sudden movement/slipping along a fault plane or the cracking of rock stressed by tectonic forces. This movement sends out seismic waves that travel through the crust potentially causing damage at the surface by a shaking or displacement of the ground.

The focus of an earthquake is the actual location of the energy released inside the Earth’s crust. The epicentre is the point on the Earth’s surface directly above the focus.
The conditions required to put rocks under the amount of stress needed to fracture them mainly occurs around the boundaries of tectonic plates. As plates push together or slide past each other they stick due to friction and then suddenly break and earthquakes are produced.

The Magnitude of an earthquake is conventionally reported using the Richter Scale. You may have noticed on the news the reporter saying “This earthquake was measured at 6.2” - they are referring to the Richter Scale. Magnitude 3 or lower earthquakes will be difficult to notice at the surface, whereas Magnitude 7 and above earthquakes will cause serious damage over a wide area. small magnitude earthquakes are a lot more common than the devastating high magnitude earthquakes. However there are still 20 > Magnitude 7 earthquakes every year!!

The San Francisco earthquake of 1906 was a major earthquake that hit San Francisco and the coast of northern California on Wednesday, April 18, 1906. The most widely accepted estimate for the magnitude of the earthquake is 7.8; however, other values have been proposed from 7.7 to as high as 8.3. The epicenter occurred offshore, about 2 miles (3 km) from the city. It ruptured along the San Andreas Fault for a total length of 296 miles (477 km). The earthquake and resulting fire is remembered as one of the worst natural disasters in the history of the USA. The death toll from the earthquake and resulting fire represents the greatest loss of life from a natural disaster in California's history. The economic impact has been compared with the more recent Hurricane Katrina disaster. 
Earthquakes are important hazards to understand as they are responsible for the deaths of the highest number of people per event for any natural hazard. They commonly strike without warning, therefore people can not evacuate to safer areas.
 Also there is not a predictable trend to the number of earthquakes per year, when and where they occur (within earthquake prone regions around tectonic plate boundaries) is randomly distributed. For example there are 1000’s of earthquakes every year, but only around 20 of them are magnitude 7 or higher. These 20 events account for 90% of the energy released from all of the earthquakes put together and result in 80% of all the earthquake fatalities.
We can not stop earthquakes from happening and we get no warning as to when they will occur….so how do we lessen the risk of earthquake activity?

The simple answer is to be prepared: In earthquake prone regions the buildings can be reinforced and designed to prevent the likelihood of collapse during an earthquake. The population can be educated about what to do in the event of an earthquake and evacuation and rescue plans can be drawn up in advance to minimise chaos and panic if/when an earthquake occurs. For example, earthquake education is now part of the curriculum in schools in some states of the USA and in Japan.

An earthquake that occurs under the ocean has the potential to form a tsunami.
Tsunami is a Japanese word with “tsu” meaning harbor and “nami” meaning wave. Not every earthquake will form a tsunami, the movement must result in the VERTICAL
DISPLACEMENT of water. That is: if a piece of the ocean floor moves either up or down (see the Extension and Compression fault examples) the ocean water will be rapidly displaced and this will form waves at the surface. If two pieces of crust slide past each other (see Transform fault example) there is no vertical movement of the crust or the overlying water and a tsunami will not form.

 The displaced water forms tsunami wave that can travel thousands of kilometers before it reaches land. The wave will break when it does eventually reach the shore potentially causing flooding as the water level rises well above normal sea level. Mud, sand and a trail of debris (trees, building material etc) is left deposited on the sea shore after the wave has subsided.
You most probably remember the 2004 South Asian Boxing Day tsunami event. This tsunami was caused by an earthquake off the coast of Sumatra that measured a magnitude of 9.2!! The biggest earthquake recorded in 40 years!

The earthquake off the Sumatran coast was originally recorded as 9.0 but has been increased to 9.2. At this magnitude it is the second largest earthquake ever recorded. This earthquake was also reported to have the longest duration of faulting, lasting between 500 and 600 seconds (8.3 to 10 minutes).
 The earthquake was so large that it caused the entire planet to vibrate as much as half an inch, or over a centimetre!! It occurred at a convergent tectonic plate boundary, where an estimated 1,600 km of faultline slipped about 15 m (a LOT of rock moved!).
 The earthquake released 20 x 1017 Joules of energy, which is like setting off 475 million kilograms of TNT or 23,000 atomic bombs!!
NOTE: The largest earthquake ever recorded, which measured 9.5, was in Chile on May 22, 1960.

The sudden vertical rise of the seabed during the earthquake displaced massive volumes of water, resulting in a tsunami that struck the coasts of 12 countries around the Indian Ocean. Because of the distances involved, the tsunami took anywhere from fifteen minutes to seven hours (for Somalia) to reach the various coastlines. The northern regions of the Indonesian island of Sumatra were hit very quickly, while Sri Lanka and the east coast of India were hit roughly 90 minutes to two hours later.
These animations show how the tsunami wave radiated out from the 1,600 km rupture in the seafloor. The red and yellow areas are those of higher than usual water levels and blue are the areas of lower than normal water levels. Note how the wave dissipates with distance, therefore the countries close to the epicentre are hit by a significantly bigger wave than those further away.

The tsunami caused widespread flooding and fatalities. Thousands of people died and many more were displaced from their homes. This photo shows an example of the devastation caused by the waves. So, we have seen that tsunami’s can be extremely devastating - but the question is, what can we do about them?

Firstly, we can monitor for them: If there is an earthquake in the ocean, specialist monitoring stations like the Pacific Tsunami Warning Centre (PTWC - pictured top right) can monitor the ocean surface using satellites, radar and buoys in the water that measure current speed and waves. These systems will pick up the presence of a tsunami. If a tsunami does occur the PTWC can warn local authorities in the areas where the tsunami is likely to hit. Computer simulations, using the speed of the tsunami wave, can estimate the time of arrival for the tsunami.
  This technology is very expensive to run and maintain however, and many poorer countries have to rely on stations from other countries that are far away. For example a tsunami that hit Papua New Guinea in 1998 was undetected as it originated close to the island and was undetected by the PTWC which is located in Hawaii. Some areas, such as Hawaii, have building restrictions in hazard prone regions. For example, tsunamis hit the town of Hilo in 1946 and 1960 destroying the harbour and a large part of the town (top photo). Now this region of the city has a ban on the construction of new buildings there and the majority of the land has been turned into a park (bottom photo). Seawalls have been constructed on many beaches not only for protection against tsunami’s but also the hazards of large storm waves.
  Seawalls are designed to make waves break early (before the shoreline), therefore dissipating their energy before they reach the shore. Some walls are designed to build up the shoreline to prevent waves from over topping the shore and flowing into residential areas.
Finally, to protect the population against tsunamis they need to be educated about the hazards involved and warning systems (sirens, emergency service teams) and evacuation plans (escape to higher ground) need to be established.
 Same Storm - Different Names…depending on where you are in the world tropical storms have different names: In the Atlantic and Pacific Oceans (eastern) they are called hurricanes. average of 10 named storms per season ~6 becoming hurricanes
•Over the western Pacific Ocean they are called typhoons.• average of 16 named storms per season •~9 becoming typhoons
•The western Pacific ocean is a major source of tropical storms as the water is warmest and there are large distances between landmasses.
•Over the Indian Ocean the storms are called cyclones. “Cyclone” is the best overall phrase to use for high intensity rotating storms.
•Storms that form north of the equator spin counterclockwise. Storms south of the equator spin clockwise. This difference is because of Earth's rotation on its axis.
•Tropical cyclones are a MAJOR natural hazard that can cause large numbers of fatalities and extensive damage. For example the 1991 Bangladesh cyclone, “Cyclone Gorky”, was among the deadliest tropical cyclones on record. On the night of the 29th of August the cyclone struck the southeastern coast of Bangladesh with winds of around 250 km/h (155 mph). The storm forced a 6 metre (20 foot) storm surge wave inland over a wide area, killing at least 138,000 people and leaving as many as 10 million homeless.
•Cyclones can devastate large areas, for example Hurricane Katrina (August 2005, USA) had gale force winds extending 120 miles (190 km) from the storm centre (“eye of the storm”) - remember cyclones are radial (circular) so that makes it approximately 240 miles (380 km) from one side to the other!
•In 1999 Hurricane Floyd caused 2.6-million coastal residents across the entire US state of Florida to evacuate their homes.
•The hurricane produced torrential rainfall that caused widespread flooding over a period of several weeks; nearly every river basin in the eastern part of the state exceeded 500-year flood levels. Hurricane Floyd was responsible for 57 fatalities and US$5.6 billion of damage.
•Tropical cyclones form only over warm ocean waters near the equator.
•To form a cyclone, warm, moist air over the ocean rises upward from near the surface. As this air moves up and away from the ocean surface, it leaves is less air near the surface. So basically as the warm air rises, it causes an area of lower air pressure below.
•Air from surrounding areas with higher air pressure pushes in to the low pressure area. Then this new “cool” air becomes warm and moist and rises, too. And the cycle continues…
•As the warmed, moist air rises and cools the water in the air forms clouds. The whole system of clouds and wind spins and grows, fed by the ocean’s heat and water evaporating from the ocean surface.
•As the storm system rotates faster and faster, an eye forms in the centre. It is very calm and clear in the eye, with very low air pressure. Higher pressure air from above flows down into the eye. When the winds in the rotating storm reach 39 mph (63 kmph), the storm is called a “tropical storm”. And when the wind speeds reach 74 mph (119 kmph), the storm is officially a “tropical cyclone” or hurricane.Tropical cyclones usually weaken when they hit land, because they are no longer being “fed” by the energy from the warm ocean waters. However, they often move far inland, dumping many centimetres of rain and causing lots of wind damage before they die out completely.
•Cyclones are divided into categories depending on the strength of the winds produced. There are many different classification scales but one you may be familiar with is the Saffir- Simpson Hurricane Scale. This scale is used to desribe storms in Hollywood movies, e.g. “Twister” and “The Day After Tomorrow”.
The classifications (1-5) are intended primarily for use in measuring the potential damage and flooding (storm surge) a cyclone will cause upon landfall.
•The students probably would have seen on the news in 2005 the devastating effect that
Hurricane Katrina had on the area of New Orleans and surrounds….
•Hurricane Katrina was the costliest and one of the deadliest hurricanes in the history of the USA.
•It was the sixth-strongest Atlantic hurricane ever recorded and the third-strongest hurricane on record that made landfall in the United States.
•Katrina formed on the 23rd of August 2005 and caused devastation along much of the northcentral Gulf Coast of the United States.
•The most severe loss of life and property damage occurred in New Orleans, which flooded as the previously emplaced flood defenses failed. The hurricane caused severe destruction across the entire coast of Mississippi and Alabama, as far as 100 miles (160 km) from the storm's centre.
•There were at least 1,836 fatalities recorded and damage estimates are over 81 billion US dollars!
We have seen that tropical storms can and do produce a lot of damage, but how is this damage produced? What are the dangers involved?
Firstly, there is the “Storm Surge”:
•A storm surge is caused by strong winds pushing on the ocean's surface. The wind causes the water to pile up higher than the ordinary sea level. Storm surges are particularly damaging when they occur at the time of a high tide, which increases the risk of flooding.
•Storm surges are extremely destructive to property, can cause flooding and large amounts of erosion.
•Storm Surges account for 90% of all fatalities associated with cyclones.
Destruction from strong winds will effect a wider region than that damaged by the storm surge. The wind can uproot trees, bring down powerlines, and damage properties.
Flying debris - enough said? Imagine being out in winds carrying building material fast 

How to do mitigate the risk from a cyclone?
•Early warning systems are needed to give people time to make their home safe (e.g. board up windows and doors), or to evacuate to a designated shelter. This may come in the forms of alarms or sirens sounded throughout a town, or notification by radio, television and local enforcement services (police, fire brigade etc.).
-Meteorological stations around the globe can trace the track of a cyclone and predict when and where the storm will make landfall. So in may cases warnings can be made in advance of the disaster.
-In cyclone-prone regions infrastructure can be emplaced to decrease the damage caused by the cyclone
-For example, “cyclone walls” (top photograph) have been built along coastal areas to stop or lessen the impact of a storm surge. These can also be used as roads along which residents can evacuate.
-In low-lying coastal regions communal storm shelters can be built. These act as an evacuation point for people living in the surrounding areas.
-For all of these measures to work the population needs to be educated about the threat of the storms and what to do in case of an emergency.
Natural Hazards such as earthquakes, tsunami’s, cyclones, volcanic eruption, avalanches and landslides, and more are a major cause of fatalities.
•This graph shows the  number of deaths per year due to natural hazards. Remember this is in addition to normal global fatalities due to age, famine, disease etc.
•Every year there are close to 10,000 fatalities caused by natural hazards. In the event of large-scale events (seen by the peaks on the graph) this number rises to ten’s of thousands!
Natural Hazards cannot be stopped, however measures can be taken to lessen the impact they have on the population. To do this we need to understand the processes involved for each type of event and work out individual emergency plans of action.
Personal Student Stories/Discussion:
•Has anyone in the class experienced a natural hazard event? Earthquake? Tsunami? Tornado? Flood? Seen a volcano erupt? Or a landslide?
•What was it like? Were there plans emplaced? Was it calm or were people panicked?
•If the students were managing the disaster plan would they have done anything differently?











ENVIRONMEN

FLOURIDE CONTAMINATION OF 

GROUND WATER 

FLUORIDE CONTAMINATION IN GROUNDWATER
M.Sc. 2NDYEAR (APPLIEDGEOLOGY)
ROLL NO - 
CONTENTS:-
Introduction
Properties offluorine
Fluoride ingroundwater
Sources
Adverseeffects
Fluoride contamination in groundwater in India,Odisha andWorld
Mitigation
References











INTRODUCTION:-





Groundwaterisconsideredasthemajorsourceofdrinkingwaterinmostplaceson earth.
Usuallypeopleusegroundwaterfordrinkingandotherdomestichouseholdpurposes such as cooking without any physical or chemicaltreatment.
•Thisisnotahealthypracticeandmayleadtonumberofhealthdisorders.However, this practice cannot be avoided due to lack of treated piped water supply system in several parts of developingcountries.
•When the chemical composition of groundwater is not within the prescribed standards for drinking or irrigation or industrial water, they become unsuitable. And excess amount of fluoride in groundwater is a major cause of pollution.

PROPERTIES OF FLUORINE:-
Fluorine belongs to halogen family represented as ‘F’ with atomic weight18.998 and atomic number9.
Itoccursasadiatomicgasinitselementalformandhasavalencenumber1.Itis the most electronegative and the most reactive when compared to all chemical elements in the periodic table (Greenwood and Earnshaw, 1984; Gillespie et al., 1989).
It has an oxidation state of -1 and occurs as both organic andinorganic compounds.
It is the 13th most abundant element in the earth’s crust (Weinstein andDavison, 2003). Its natural abundance in the earth’s crust is 0.06 to 0.09% (Fawell et al., 2006) and the average crustal abundance is 300 mg/kg (Tebutt,1983).








Fluoride does not exhibit any colour, taste or smell when dissolved in water. Hence, it is not easy to determine it through physical examination. Only chemical analysis of the groundwater samples can determine the concentration of thision.

FLUORIDE IN GROUNDWATER
Groundwater with fluoride concentration above the permissible limit setby WHO i.e 1.5 mg/l have been recorded in several parts of theworld.
In 1984, WHO estimated that more than 260 million people living all overthe world consume water with fluoride concentration above 1 mg/l (WHO, 1984).
The problem of high fluoride in groundwater has been reported by several researchers in India, China, Japan, Sri Lanka, Iran, Pakistan, Turkey, Southern Algeria, Mexico, Korea, Italy, Brazil, Malawi, North Jordan, Ethiopia, Canada, Norway, Ghana, Kenya, South Carolina, Wisconsin and Ohio.








Most of the people affected by high fluoride concentration in groundwater live in the tropical countries where the per capita consumption of water is more because of the prevailingclimate.
In places like Ghana, people consume 3 to 4 liters of water which is higher than the WHO estimate of 2 l/adult/day (Apambire et al.,1997).
The risk of fluorosis is higher in these places. However, incidence of fluorosis in people living in other parts of the world has also been reported. The intensity of fluorosis problem is very serious in the two heavily populated countries of the world namely India and China (Ayoob and Gupta,2006).

SOURCES OF FLUORIDE IN GROUNDWATER
Aquifer material:-
•Most of the fluoride in groundwater is naturally present due to weathering of rocks rich in fluoride.Waterwithhighconcentrationoffluorideismostlyfoundinsedimentsofmarine origin and at the foot of mountainous areas.
•Fluoride occurs as sellaite , fluorite or fluorspar , cryolite , fluorapatite , apatite , topaz , fluormica(phlogopite),biotite,epidote,amphibolesuchastremoliteandhornblende,mica, clays, villuanite andphosphorite.
Granitic rocks which are a typical source of fluoride rich rocks contain fluoride ranging between500and1400mg/kg,whichismuchhigherthananyotherrocktype.Theworld average content of fluoride in granitic rocks is 810 mg/kg . The weathering of these rocks results in increased fluoride content ingroundwater.

Volcanic ash:-



Volcanic rocks are often enriched in fluoride. Hydrogen fluorine isone of the most soluble gases in magmas and comes out partially during eruptive activity.
The aerial emission of fluoride in the form of volcanic ash during volcanic eruption reaches the surface by fall out of particulate fluorides and during rainfall. This fluoride from the soil surface will easily reach the groundwater zone along with percolatingrainwater.
Volcanic ash is readily soluble and thus the risk offluoride contamination in groundwater is veryhigh.

Fly ash:-



Like volcanic ash, fly ash from the combustion of fossil fuels also account for high fluoride. More than 100 to 150 million tons of fly ash is produced worldwide annually due to the combustion of coal especially from power plants . Inappropriate disposal of this fly ash will result in the  leaching of fluoride togroundwater.

Fertilisers:-
Phosphate containing fertilisers add up to the fluoride content in soil and groundwater . It is evident that superphosphate (2750 mg of F/kg), potash (10 mg of F /kg) and NPK (Nitrogen Phosphorous Potassium) (1675 mg of F /kg) which are phosphatic fertilisers contain remarkable amount of fluoride. In agricultural areas successive irrigation had lead to the increase in fluoride concentration ingroundwater

Adverse effects:-
Intake of fluoride higher than the optimum level is the main reason for dental and skeletal fluorosis. Depending upon the dosage and the period of exposure fluorosis may be acute tochronic.
In India 62 million people including 6 million children are estimated to have serious health problemsduetoconsumptionoffluoridecontaminatedwater(AndezhathandGosh,2000).
The health outcome by consuming fluoride at different concentration was given by Dissanayake (1991) i.e. when fluoride concentration in drinking water is below 0.5 mg/l it causes dental carries; fluoride between 0.5 to 1.5 mg/l results in optimum dental health; 1.5 to 4 mg/l causes dental fluorosis; 4 to 10 mg/l induces dental and skeletal fluorosis while fluoride above 10 mg/l results in cripplingfluorosis.

Dental fluorosis
Tooth enamel is principally made up of hydroxyapatite (87%) which is crystalline calcium phosphate . Fluoride which is more stable than hydroxyapatite displaces the hydroxide ions from hydroxyapatite to form fluoroapatite. On prolonged continuation of this process the teeth become hard and brittle. This is called dentalfluorosis.
Dental fluorosis in the initial stages results in the tooth becoming coloured from yellow to brown to black. Depending upon the severity, it may be only discolouration of the teeth or formation of pits in theteeth.
The colouration on the teeth may be in the form of spots or as streaks. Usually these streaks on the teeth arehorizontal.



Skeletal fluorosis:-
Exposure to very high fluoride over a prolonged period of time results in acute to chronic skeletalfluorosis.
Early stages of skeletal fluorosis start with pain in bones and joints, muscle weakness, sporadic pain, stiffness of joints and chronicfatigue.
During later stages, calcification of the bones takes place, osteoporosis in long bones, and symptoms of osteosclerosis where the bones become denser and develop abnormal crystallinestructure.








Inthe advanced stage the bones and joints become completely weak and moving them is difficult. The vertebrae in the spine fusetogether and the patient is left crippled which is the final stage. Skeletal fluorosis is usually not recognized until the disease reaches an advancedstage.
Skeletal fluorosis does not only affect humans but also animals fed with fluoride rich water andfodder.









Other effects:-
Other health disorders that occur due to consumption of high fluoride in drinking water to be muscle fibre degeneration, low haemoglobin levels, deformities in RBCs, excessive thirst, headache, skin rashes, nervousness, neurological manifestations, depression, gastrointestinal problems, urinary tract malfunctioning, nausea, abdominal pain, tingling sensation in fingers and toes,reducedimmunity,repeatedabortionsorstillbirths,malesterility,etc.
As fluoride is excreted in urine through the kidneys, they affect the effective functioningofthekidneys.Theyfacilitateintheformationofkidneystones.








Consumption of drinking water with high fluoride by childrenmay affect theirintelligence.
The presence of excessive fluoride in groundwater has its impact not only on humans but also on soil fertility and plant and animalgrowth.

Fluoridecontaminationin groundwaterin India:-
Of the 85 million tons of fluoride deposits on the earth’s crust, 12 million are found in India (Teotia and Teotia, 1994). Hence it is natural that fluoride contamination is widespread, intensive and alarming inIndia.
Some regions in north western and southern India are heavily affected with fluorosis (Agarwal et al., 1997; Yadav et al., 1999). About 50% of the groundwater in Delhi exceeds the maximum permissible limit for fluoride in drinking water (Datta et al.,1996).
Jacks et al. (2005) observed that high fluoride in groundwater in many parts of India was due to evapotranspiration of groundwater with residualalkalinity.








Fluoride content was higher in deeper aquifers of Maharashtra (Madhnure et al., 2007) which was due to long residence time than shallowgroundwater.
The rocks in southern India are rich with fluoride which forms the major reason for fluoride contamination ingroundwater.
It is a well established fact that groundwater in Nalgonda district, Andhra Pradesh, has high fluoride due to the inherent fluoride rich graniticrocks
The granitic rocks in Nalgonda district contain fluoride from 325 to 3200 mg/kg with a mean of 1440mg/kg.








The Nalgonda Granties contain much higher fluoride than theworld average fluoride concentration of 810 mg/kg (Wedepohl,1969).
Thus treatment of groundwater especially for fluoride before using it for drinking purpose is very essential inIndia.







Fluorideconcentration in groundwaterin Odisha:-

















Mitigation measures:-
Insitu-treatment methods :-
Insitu method aims at directly diluting the concentration of fluoride (in groundwater) in the aquifer. This can be achieved by artificialrecharge.
Construction of check dams in Anantapur district, India has helped widely to reduce fluoride concentration in groundwater (Bhagavan and Raghu,2005).
Rainfall recharge also called as rainwater harvesting can be adopted using percolation tanks and recharge pits which may prove helpful. Recharge of rainwater after filtration through the existing wells can also be planned to improve the groundwaterquality.


Exsitu-treatment methods:-


Adsorption method involves the passage of water through a contact bed where fluoride is adsorbedonthematrix.Activatedcharcoalandactivatedaluminaarethewidelyusedadsorbents.
Brick, bone char, fly ash, serpentine, red mud, waste mud, rice husk, kaolinite, bentonite, charfines, ceramic etc. are some of the other absorbents capable of effectively removing fluoride fromgroundwater.
In ion exchange process, when water passes through a column containing ion exchange resin, the fluoride ions replace calcium ions in theresin.
Once the resin is saturated with fluoride ions, it is backwashed with solution containing chloride such as sodiumchloride.








The chloride ions thus again replaces the fluoride ions in the resin and is ready for reuse. But the backwash is rich in fluoride and hence care should be taken in disposing this solution.
Similarly in precipitation methods, the disposal of sludge with concentrated fluoride is a great problem. Precipitation involves addition of chemicals such as calcium which results in the precipitation of fluoride as fluorite. Aluminium salts are also used for thisprocess.
Membrane processes is also an ex-situ technique which includes methods called reverse osmosis and electrodialysis. These are advanced techniques which require high costinput.








Apart from all these it is essential to create environmental awareness among public regarding the ill effects of high fluoride. Reduction in the use of fertilisers, especially phosphatic fertilisers is important. It is better to adopt organic farming in places of fluoridethreat.
Usage of coal for combustion indoors should be avoided and the resultant fly ash obtained from combustion of fossil fuel in industries has to be disposedcautiously.
In countries with high temperature, it is advisable to reduce evapotranspiration by increasing vegetation cover. This will prevent the deposition of fluoride salts on the unsaturated zone which will subse